Chloride stress corrosion cracking polythionic acid stress. Amine corrosion refers to the general andor localized corrosion that occurs principally on carbon steel in amine treating processes. The diaphragm is susceptible to this failure mode due to its high residual stress. It was revealed that the pwscc fracture mode of these materials changed. Chemical studies of polythionic acid stresscorrosion cracking. Low temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous solutions of polythionates sxo62. Bradley and others published alloy for resistance to polythionic acid stress corrosion cracking for hydroprocessing.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Api 571 icp corrosion and materials archives wilkinson. The cracks are intergranular and narrow with no significant branching. Pascc stands for polythionic acid stress corrosion cracking oil refining. Stress corrosion cracking of ring type joint of reactor pipeline of a hydrocracker unit p. Stress relaxation cracking of welded joints in thick. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. Cracking is due to sulfur acids forming from sulfide scale, air and moisture acting on sensitized austenitic stainless steels. On the mechanism of intergranular stress corrosion. Polythionic acid is formed by the reaction of sulphide scale, oxygen and water.
Stress corrosion cracking scc is one of the most prevalent root causes of stainless steel failures in the refining industry. The presence of flaws that concentrate stress or crevices that alter. Sp0403 avoiding caustic stress corrosion cracking of refinery equipment and piping. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. The importance of a conjoint action of corrosion and stress as well as the nature of. Wet h2s cracking reheat cracking sulfuric acid corrosion polythionic acid stress corrosion cracking dissimilar metal weld dmw cracking co2 corrosion corrosion under insulation cui caustic corrosion. The crevice between the diaphragm and channel contain concentrated chlorides and aggravate the cracking mechanism. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Polythionic acid stress corrosion cracking a form of stress corrosion cracking normally occurring during shutdowns, startups or during operation when air and moisture are present. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail.
Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. Cracking mechanism an overview sciencedirect topics. All of the cracks observed were found underneath the coke deposits. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid.
Identifying and mitigating existing or potential damage mechanisms are important parts of an effective mechanical integrity program. Pdf refinery hydroprocessors are subject to a variety of corrosion. How is polythionic acid stress corrosion cracking oil refining abbreviated. What are the industrial practices being followed in.
Stress corrosion cracking of sensitized type 304 stainless steel in thiosulfate solutions r. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Cracks that propagated through welds had a very brittle appearance, most probably due to the very poor creep rupture ductility of e34716 welds. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Polythionic acid stress corrosion cracking of type 310 stainless steel. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube.
Once the metal is sensitized, sulfide scale on the metal can react with moisture and air, typically during shutdowns, to form polythionic acid. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Importantly, the selection of 300 ss would also introduce a new damage mechanism to the crude unit in the form of stress corrosion cracking scc from chlorides, and potentially from polythionic acids, that would not occur with 9cr. It has been shown that, for some materials, fine pitting is needed to start the activity. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx.
Ctlpolythionic stress corrosion cracking of stainless. Then sulfide scales react with oxygen and polythionic acid is produced, leading to cracking in the presence of residual internal stresses at the sensitized material of the reactor tube. In this chapter, the conditions for the occurrence of scc are first introduced. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304. Cracking mechanisms in which corrosion is implicated include stress corrosion cracking, corrosion fatigue, hydrogeninduced cracking and liquid metal embrittlement. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to. Based on this analysis the leaks were caused by cracks that initiated on the id surface.
Stresscorrosion cracking of sensitized type 304 stainless. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Pascc polythionic acid stress corrosion cracking oil. Pdf polythionic acid corrosion in refinery hydroprocessors. The probable role of low levels of chloride ions or sulfurcontaining ions is described, including the relationship of the phenomenon to polythionic acid cracking. The interaction of corrosion fatigue and stresscorrosion.
Alloy for resistance to polythionic acid stress corrosion. Sulfur can come from feed stock, additives or fuels. This failure mechanism is possible from both inside and outside of a tube, depending on the sulfur source. Samans, stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution, corrosion. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. During the scc test, the steel specimen was subjected to threepoint bending with constant strain at room temperature, and. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking.
This damage mechanism primarily affects standard and high carbon stainless. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Stress corrosion cracking of ring type joint of reactor. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Alloy for resistance to polythionic acid stress corrosion cracking for. Cracking of sensitized stainless steels inspectioneering. Purely mechanical forms of cracking such as brittle failure and fatigue are not considered here. Assessing stress corrosion cracking risks on stainless. Chloride stress corrosion cracking polythionic acid stress corrosion cracking from mechanical 1011 at albany state university. Polythionic acid stress corrosion cracking pascc is a type of intergranular. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
Michael j schofield bsc, msc, phd, mim, ceng, in plant engineers reference book second edition, 2002. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Stress corrosion cracking susceptibility of stainless. Stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution c. The item was exposed to sulfur containing natural gas in a continuous flare. Polythionic acid stress corrosion cracking deterioration. The conjoint action of a tensile stress and a specific corrodent on a material results in stress corrosion cracking scc if the conditions are sufficiently severe. Polythionic acid stress corrosion cracking hydrotreater effluent systems use austenitic ss for sulfidation resistance. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass. Corrosion is not caused by the amine itself, but results from dissolved acid.
Why does chloride stress corrosion cracking and pascc only. Two examples of stress corrosion cracking scc in refinery equipment are presented. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Effect of strain rate on primary water stress corrosion. For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. A tetrathionic potassium k 2 s 4 o 6 chemical solution was used to mimic polythionic acid scc which the most aggressive scc type. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula s n so 3 h 2 n 2. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these. It can cause corrosion of austenitic stainless steel radiant tubes during furnace cooldown if the furnace tubes have become sensitised in operation. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Intergranular stress corrosion cracking scc mechanism in sensitized stainless steel type 304 was investigated experimentally. Sp0170 protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment sp0296 detection, repair, and mitigation of cracking in refinery equipment in wet h2s environments. Trithionic acid h 2 s 3 o 6, tetrathionic acid h 2 s 4 o 6 are simple examples. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. Table 2 spectrochemical analysis of ring and flange material composition. The tensile stress can be the residual stress in a fabricated structure, the hoop stress in a pipe containing fluid at pressures above ambient or in a vessel by virtue of the internal hydraulic pressure created by the weight of its contents. No need to neutralize when exposed to sensitization conditions and h2s to prevent polythionic acid stress corrosion cracking. Further progress is then a process alternating between corrosion and mechanical cracking. Preface thispresentvolumeisthefirstofatwopartseriesonstresscorrosioncrackingplannedbythe advancedresearchprojectsagencyforthedesigner.
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